Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst
Nema prikaza
Autori
Ajdačić, VladimirNikolić, Andrea
Simić, Stefan
Manojlović, Dragan
Stojanović, Zoran
Nikodinović-Runić, Jasmina
Opsenica, Igor M.
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
A facile decarbonylation reaction of a variety of aromatic and heteroaromatic aldehydes using maghemite-supported palladium catalyst has been developed. The magnetic properties of catalyst facilitated an easy and efficient recovery of the catalyst from the reaction mixture using an external magnet. It was found that the catalyst could be reused up to four consecutive catalytic runs without a significant change in activity. In addition, the catalyst was also very effective in the dehalogenation of aryl halides. This is the first report on efficient utilization of directly immobilized Pd on maghemite in decarbonylation and dehalogenation reactions.
Ključne reči:
palladium catalyst / magnetically recoverable catalyst / maghemite / dehalogenation / decarbonylationIzvor:
Synthesis-Stuttgart, 2018, 50, 1, 119-126Izdavač:
- Georg Thieme Verlag Kg, Stuttgart
Finansiranje / projekti:
- Sinteza aminohinolina i njihovih derivata kao antimalarika i inhibitora botulinum neurotoksina A (RS-MESTD-Basic Research (BR or ON)-172008)
- Molekularno dizajniranje nanočestica kontrolisanih morfoloških i fizičko-hemijskih karakteristika i funkcionalnih materijala na njihovoj osnovi (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45004)
DOI: 10.1055/s-0036-1590892
ISSN: 0039-7881
WoS: 000418280600010
Scopus: 2-s2.0-85038632737
Institucija/grupa
Institut za molekularnu genetiku i genetičko inženjerstvoTY - JOUR AU - Ajdačić, Vladimir AU - Nikolić, Andrea AU - Simić, Stefan AU - Manojlović, Dragan AU - Stojanović, Zoran AU - Nikodinović-Runić, Jasmina AU - Opsenica, Igor M. PY - 2018 UR - https://imagine.imgge.bg.ac.rs/handle/123456789/1171 AB - A facile decarbonylation reaction of a variety of aromatic and heteroaromatic aldehydes using maghemite-supported palladium catalyst has been developed. The magnetic properties of catalyst facilitated an easy and efficient recovery of the catalyst from the reaction mixture using an external magnet. It was found that the catalyst could be reused up to four consecutive catalytic runs without a significant change in activity. In addition, the catalyst was also very effective in the dehalogenation of aryl halides. This is the first report on efficient utilization of directly immobilized Pd on maghemite in decarbonylation and dehalogenation reactions. PB - Georg Thieme Verlag Kg, Stuttgart T2 - Synthesis-Stuttgart T1 - Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst EP - 126 IS - 1 SP - 119 VL - 50 DO - 10.1055/s-0036-1590892 ER -
@article{ author = "Ajdačić, Vladimir and Nikolić, Andrea and Simić, Stefan and Manojlović, Dragan and Stojanović, Zoran and Nikodinović-Runić, Jasmina and Opsenica, Igor M.", year = "2018", abstract = "A facile decarbonylation reaction of a variety of aromatic and heteroaromatic aldehydes using maghemite-supported palladium catalyst has been developed. The magnetic properties of catalyst facilitated an easy and efficient recovery of the catalyst from the reaction mixture using an external magnet. It was found that the catalyst could be reused up to four consecutive catalytic runs without a significant change in activity. In addition, the catalyst was also very effective in the dehalogenation of aryl halides. This is the first report on efficient utilization of directly immobilized Pd on maghemite in decarbonylation and dehalogenation reactions.", publisher = "Georg Thieme Verlag Kg, Stuttgart", journal = "Synthesis-Stuttgart", title = "Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst", pages = "126-119", number = "1", volume = "50", doi = "10.1055/s-0036-1590892" }
Ajdačić, V., Nikolić, A., Simić, S., Manojlović, D., Stojanović, Z., Nikodinović-Runić, J.,& Opsenica, I. M.. (2018). Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst. in Synthesis-Stuttgart Georg Thieme Verlag Kg, Stuttgart., 50(1), 119-126. https://doi.org/10.1055/s-0036-1590892
Ajdačić V, Nikolić A, Simić S, Manojlović D, Stojanović Z, Nikodinović-Runić J, Opsenica IM. Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst. in Synthesis-Stuttgart. 2018;50(1):119-126. doi:10.1055/s-0036-1590892 .
Ajdačić, Vladimir, Nikolić, Andrea, Simić, Stefan, Manojlović, Dragan, Stojanović, Zoran, Nikodinović-Runić, Jasmina, Opsenica, Igor M., "Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst" in Synthesis-Stuttgart, 50, no. 1 (2018):119-126, https://doi.org/10.1055/s-0036-1590892 . .