Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials
Само за регистроване кориснике
2020
Аутори
Jaksić, JovanaOstojić, Sanja
Micić, Darko
Vujosević, Zorana Tokic
Milovanović, Jelena
Karkalić, Radovan
O'Connor, Kevin
Kenny, Shane T.
Casey, William
Nikodinović-Runić, Jasmina
Maslak, Veselin
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
In the present work, we describe the chemical synthesis of 3-HFAs as prominent derivatives of fatty acids and assess if they could be applied as phase change materials (PCM). In addition, 3-HFAs were obtained by depolymerization of a bacterial biopolymeric material, polyhydroxyalkanoate. Thermal properties of 3-hydoxyoctanoic, decanoic, and dodecanoic acids are reported for the first time. These materials showed the potential to be applied as PCM in temperature range from 33 degrees C to 66 degrees C. In order to expand the temperature range for application of 3-HFAs as PCM, eutectic mass ratios of three kinds of binary mixtures of 3-HFAs were calculated, and their properties were predicted using the Schroder-van Laar equation. Thermal properties of these mixtures were validated by differential scanning calorimetry (DSC) analysis. These results showed that eutectics considerably expanded the scope of applications of 3-HFAs as PCMs. 3-HFAs originating from biotechnologically obtained po...lyhydroxyalkanoates also showed potential to be applied in development of PCMs.
Кључне речи:
thermophysical properties / phase change materials / eutectic mixtures / biopolymer / 3-hydroxy fatty acidsИзвор:
International Journal of Energy Research, 2020, 44, 2, 1294-1302Издавач:
- Hoboken : Wiley
Финансирање / пројекти:
- Bioplastech Industrial Collaboration [BP2017]
- Дизајн, синтеза и испитивање наномолекулских машина на бази фулерена (RS-MESTD-Basic Research (BR or ON)-172002)
DOI: 10.1002/er.4934
ISSN: 0363-907X
WoS: 000495538000001
Scopus: 2-s2.0-85075197383
Институција/група
Institut za molekularnu genetiku i genetičko inženjerstvoTY - JOUR AU - Jaksić, Jovana AU - Ostojić, Sanja AU - Micić, Darko AU - Vujosević, Zorana Tokic AU - Milovanović, Jelena AU - Karkalić, Radovan AU - O'Connor, Kevin AU - Kenny, Shane T. AU - Casey, William AU - Nikodinović-Runić, Jasmina AU - Maslak, Veselin PY - 2020 UR - https://imagine.imgge.bg.ac.rs/handle/123456789/1399 AB - In the present work, we describe the chemical synthesis of 3-HFAs as prominent derivatives of fatty acids and assess if they could be applied as phase change materials (PCM). In addition, 3-HFAs were obtained by depolymerization of a bacterial biopolymeric material, polyhydroxyalkanoate. Thermal properties of 3-hydoxyoctanoic, decanoic, and dodecanoic acids are reported for the first time. These materials showed the potential to be applied as PCM in temperature range from 33 degrees C to 66 degrees C. In order to expand the temperature range for application of 3-HFAs as PCM, eutectic mass ratios of three kinds of binary mixtures of 3-HFAs were calculated, and their properties were predicted using the Schroder-van Laar equation. Thermal properties of these mixtures were validated by differential scanning calorimetry (DSC) analysis. These results showed that eutectics considerably expanded the scope of applications of 3-HFAs as PCMs. 3-HFAs originating from biotechnologically obtained polyhydroxyalkanoates also showed potential to be applied in development of PCMs. PB - Hoboken : Wiley T2 - International Journal of Energy Research T1 - Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials EP - 1302 IS - 2 SP - 1294 VL - 44 DO - 10.1002/er.4934 ER -
@article{ author = "Jaksić, Jovana and Ostojić, Sanja and Micić, Darko and Vujosević, Zorana Tokic and Milovanović, Jelena and Karkalić, Radovan and O'Connor, Kevin and Kenny, Shane T. and Casey, William and Nikodinović-Runić, Jasmina and Maslak, Veselin", year = "2020", abstract = "In the present work, we describe the chemical synthesis of 3-HFAs as prominent derivatives of fatty acids and assess if they could be applied as phase change materials (PCM). In addition, 3-HFAs were obtained by depolymerization of a bacterial biopolymeric material, polyhydroxyalkanoate. Thermal properties of 3-hydoxyoctanoic, decanoic, and dodecanoic acids are reported for the first time. These materials showed the potential to be applied as PCM in temperature range from 33 degrees C to 66 degrees C. In order to expand the temperature range for application of 3-HFAs as PCM, eutectic mass ratios of three kinds of binary mixtures of 3-HFAs were calculated, and their properties were predicted using the Schroder-van Laar equation. Thermal properties of these mixtures were validated by differential scanning calorimetry (DSC) analysis. These results showed that eutectics considerably expanded the scope of applications of 3-HFAs as PCMs. 3-HFAs originating from biotechnologically obtained polyhydroxyalkanoates also showed potential to be applied in development of PCMs.", publisher = "Hoboken : Wiley", journal = "International Journal of Energy Research", title = "Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials", pages = "1302-1294", number = "2", volume = "44", doi = "10.1002/er.4934" }
Jaksić, J., Ostojić, S., Micić, D., Vujosević, Z. T., Milovanović, J., Karkalić, R., O'Connor, K., Kenny, S. T., Casey, W., Nikodinović-Runić, J.,& Maslak, V.. (2020). Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials. in International Journal of Energy Research Hoboken : Wiley., 44(2), 1294-1302. https://doi.org/10.1002/er.4934
Jaksić J, Ostojić S, Micić D, Vujosević ZT, Milovanović J, Karkalić R, O'Connor K, Kenny ST, Casey W, Nikodinović-Runić J, Maslak V. Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials. in International Journal of Energy Research. 2020;44(2):1294-1302. doi:10.1002/er.4934 .
Jaksić, Jovana, Ostojić, Sanja, Micić, Darko, Vujosević, Zorana Tokic, Milovanović, Jelena, Karkalić, Radovan, O'Connor, Kevin, Kenny, Shane T., Casey, William, Nikodinović-Runić, Jasmina, Maslak, Veselin, "Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials" in International Journal of Energy Research, 44, no. 2 (2020):1294-1302, https://doi.org/10.1002/er.4934 . .