TY  - JOUR
AU  - Stevanović, Nevena Lj.
AU  - Andrejević, Tina P.
AU  - Crochet, Aurelien
AU  - Ilić-Tomić, Tatjana
AU  - Drasković, Nenad S.
AU  - Nikodinović-Runić, Jasmina
AU  - Fromm, Katharina M.
AU  - Djuran, Milos 
AU  - Glišić, Biljana
PY  - 2019
UR  - https://imagine.imgge.bg.ac.rs/handle/123456789/1222
AB  - The reactions between equimolar amounts of CuX2 (X = NO3- and CF3SO3-) and two aromatic nitrogen-containing heterocycles differing in the position of nitrogen atoms, 1,7- and 4,7-phenanthroline (1,7-and 4,7-phen), were performed in ethanol/methanol at room temperature. When CuX 2 salts were mixed with 4,7-phen, two copper(II) complexes, [Cu(NO3)(2)(4,7-Hphen)(2)](NO3)(2) (1) and [Cu(CF3SO3)(4,7-phen)(2)(H2O)(2)]CF3SO3 (2), were formed. On the other hand, in the reaction of CuX2 salts with 1,7-phen, only 1,7-HphenNO(3) (3a/b) and 1,7-HphenCF(3)SO(3) (4) were obtained as the final products. The obtained products 1-4 were characterized by spectroscopic and X-ray diffraction techniques. In the copper(II) complexes 1 and 2, the coordination geometry around the Cu(II) ion is distorted octahedral and square pyramidal, respectively. The antimicrobial potential of the copper(II) complexes 1 and 2 and corresponding compounds used for their synthesis were assessed against four different bacterial species and Candida albicans, displaying moderate growth inhibiting activity. The cytotoxic properties of the investigated complexes were also evaluated against the normal human lung fibroblast cell line (MRC-5) indicating moderate, yet more pronounced cytotoxicity than antimicrobial properties.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Polyhedron
T1  - Different coordination abilities of 1,7-and 4,7-phenanthroline in the reactions with copper(II) salts: Structural characterization and biological evaluation of the reaction products
VL  - 173
DO  - 10.1016/j.poly.2019.114112
ER  - 

@article{
author = "Stevanović, Nevena Lj. and Andrejević, Tina P. and Crochet, Aurelien and Ilić-Tomić, Tatjana and Drasković, Nenad S. and Nikodinović-Runić, Jasmina and Fromm, Katharina M. and Djuran, Milos  and Glišić, Biljana",
year = "2019",
abstract = "The reactions between equimolar amounts of CuX2 (X = NO3- and CF3SO3-) and two aromatic nitrogen-containing heterocycles differing in the position of nitrogen atoms, 1,7- and 4,7-phenanthroline (1,7-and 4,7-phen), were performed in ethanol/methanol at room temperature. When CuX 2 salts were mixed with 4,7-phen, two copper(II) complexes, [Cu(NO3)(2)(4,7-Hphen)(2)](NO3)(2) (1) and [Cu(CF3SO3)(4,7-phen)(2)(H2O)(2)]CF3SO3 (2), were formed. On the other hand, in the reaction of CuX2 salts with 1,7-phen, only 1,7-HphenNO(3) (3a/b) and 1,7-HphenCF(3)SO(3) (4) were obtained as the final products. The obtained products 1-4 were characterized by spectroscopic and X-ray diffraction techniques. In the copper(II) complexes 1 and 2, the coordination geometry around the Cu(II) ion is distorted octahedral and square pyramidal, respectively. The antimicrobial potential of the copper(II) complexes 1 and 2 and corresponding compounds used for their synthesis were assessed against four different bacterial species and Candida albicans, displaying moderate growth inhibiting activity. The cytotoxic properties of the investigated complexes were also evaluated against the normal human lung fibroblast cell line (MRC-5) indicating moderate, yet more pronounced cytotoxicity than antimicrobial properties.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Different coordination abilities of 1,7-and 4,7-phenanthroline in the reactions with copper(II) salts: Structural characterization and biological evaluation of the reaction products",
volume = "173",
doi = "10.1016/j.poly.2019.114112"
}

Stevanović, N. Lj., Andrejević, T. P., Crochet, A., Ilić-Tomić, T., Drasković, N. S., Nikodinović-Runić, J., Fromm, K. M., Djuran, M.,& Glišić, B.. (2019). Different coordination abilities of 1,7-and 4,7-phenanthroline in the reactions with copper(II) salts: Structural characterization and biological evaluation of the reaction products. in Polyhedron
Pergamon-Elsevier Science Ltd, Oxford., 173.
https://doi.org/10.1016/j.poly.2019.114112

Stevanović NL, Andrejević TP, Crochet A, Ilić-Tomić T, Drasković NS, Nikodinović-Runić J, Fromm KM, Djuran M, Glišić B. Different coordination abilities of 1,7-and 4,7-phenanthroline in the reactions with copper(II) salts: Structural characterization and biological evaluation of the reaction products. in Polyhedron. 2019;173.
doi:10.1016/j.poly.2019.114112 .

Stevanović, Nevena Lj., Andrejević, Tina P., Crochet, Aurelien, Ilić-Tomić, Tatjana, Drasković, Nenad S., Nikodinović-Runić, Jasmina, Fromm, Katharina M., Djuran, Milos , Glišić, Biljana, "Different coordination abilities of 1,7-and 4,7-phenanthroline in the reactions with copper(II) salts: Structural characterization and biological evaluation of the reaction products" in Polyhedron, 173 (2019),
https://doi.org/10.1016/j.poly.2019.114112 . .