Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials
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2020
Authors
Jaksić, JovanaOstojić, Sanja
Micić, Darko
Vujosević, Zorana Tokic
Milovanović, Jelena
Karkalić, Radovan
O'Connor, Kevin
Kenny, Shane T.
Casey, William
Nikodinović-Runić, Jasmina
Maslak, Veselin
Article (Published version)
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Show full item recordAbstract
In the present work, we describe the chemical synthesis of 3-HFAs as prominent derivatives of fatty acids and assess if they could be applied as phase change materials (PCM). In addition, 3-HFAs were obtained by depolymerization of a bacterial biopolymeric material, polyhydroxyalkanoate. Thermal properties of 3-hydoxyoctanoic, decanoic, and dodecanoic acids are reported for the first time. These materials showed the potential to be applied as PCM in temperature range from 33 degrees C to 66 degrees C. In order to expand the temperature range for application of 3-HFAs as PCM, eutectic mass ratios of three kinds of binary mixtures of 3-HFAs were calculated, and their properties were predicted using the Schroder-van Laar equation. Thermal properties of these mixtures were validated by differential scanning calorimetry (DSC) analysis. These results showed that eutectics considerably expanded the scope of applications of 3-HFAs as PCMs. 3-HFAs originating from biotechnologically obtained po...lyhydroxyalkanoates also showed potential to be applied in development of PCMs.
Keywords:
thermophysical properties / phase change materials / eutectic mixtures / biopolymer / 3-hydroxy fatty acidsSource:
International Journal of Energy Research, 2020, 44, 2, 1294-1302Publisher:
- Hoboken : Wiley
Funding / projects:
- Bioplastech Industrial Collaboration [BP2017]
- Design, synthesis and investigations of fullerene based nanomolecular machines (RS-MESTD-Basic Research (BR or ON)-172002)
DOI: 10.1002/er.4934
ISSN: 0363-907X
WoS: 000495538000001
Scopus: 2-s2.0-85075197383
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Institut za molekularnu genetiku i genetičko inženjerstvoTY - JOUR AU - Jaksić, Jovana AU - Ostojić, Sanja AU - Micić, Darko AU - Vujosević, Zorana Tokic AU - Milovanović, Jelena AU - Karkalić, Radovan AU - O'Connor, Kevin AU - Kenny, Shane T. AU - Casey, William AU - Nikodinović-Runić, Jasmina AU - Maslak, Veselin PY - 2020 UR - https://imagine.imgge.bg.ac.rs/handle/123456789/1399 AB - In the present work, we describe the chemical synthesis of 3-HFAs as prominent derivatives of fatty acids and assess if they could be applied as phase change materials (PCM). In addition, 3-HFAs were obtained by depolymerization of a bacterial biopolymeric material, polyhydroxyalkanoate. Thermal properties of 3-hydoxyoctanoic, decanoic, and dodecanoic acids are reported for the first time. These materials showed the potential to be applied as PCM in temperature range from 33 degrees C to 66 degrees C. In order to expand the temperature range for application of 3-HFAs as PCM, eutectic mass ratios of three kinds of binary mixtures of 3-HFAs were calculated, and their properties were predicted using the Schroder-van Laar equation. Thermal properties of these mixtures were validated by differential scanning calorimetry (DSC) analysis. These results showed that eutectics considerably expanded the scope of applications of 3-HFAs as PCMs. 3-HFAs originating from biotechnologically obtained polyhydroxyalkanoates also showed potential to be applied in development of PCMs. PB - Hoboken : Wiley T2 - International Journal of Energy Research T1 - Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials EP - 1302 IS - 2 SP - 1294 VL - 44 DO - 10.1002/er.4934 ER -
@article{ author = "Jaksić, Jovana and Ostojić, Sanja and Micić, Darko and Vujosević, Zorana Tokic and Milovanović, Jelena and Karkalić, Radovan and O'Connor, Kevin and Kenny, Shane T. and Casey, William and Nikodinović-Runić, Jasmina and Maslak, Veselin", year = "2020", abstract = "In the present work, we describe the chemical synthesis of 3-HFAs as prominent derivatives of fatty acids and assess if they could be applied as phase change materials (PCM). In addition, 3-HFAs were obtained by depolymerization of a bacterial biopolymeric material, polyhydroxyalkanoate. Thermal properties of 3-hydoxyoctanoic, decanoic, and dodecanoic acids are reported for the first time. These materials showed the potential to be applied as PCM in temperature range from 33 degrees C to 66 degrees C. In order to expand the temperature range for application of 3-HFAs as PCM, eutectic mass ratios of three kinds of binary mixtures of 3-HFAs were calculated, and their properties were predicted using the Schroder-van Laar equation. Thermal properties of these mixtures were validated by differential scanning calorimetry (DSC) analysis. These results showed that eutectics considerably expanded the scope of applications of 3-HFAs as PCMs. 3-HFAs originating from biotechnologically obtained polyhydroxyalkanoates also showed potential to be applied in development of PCMs.", publisher = "Hoboken : Wiley", journal = "International Journal of Energy Research", title = "Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials", pages = "1302-1294", number = "2", volume = "44", doi = "10.1002/er.4934" }
Jaksić, J., Ostojić, S., Micić, D., Vujosević, Z. T., Milovanović, J., Karkalić, R., O'Connor, K., Kenny, S. T., Casey, W., Nikodinović-Runić, J.,& Maslak, V.. (2020). Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials. in International Journal of Energy Research Hoboken : Wiley., 44(2), 1294-1302. https://doi.org/10.1002/er.4934
Jaksić J, Ostojić S, Micić D, Vujosević ZT, Milovanović J, Karkalić R, O'Connor K, Kenny ST, Casey W, Nikodinović-Runić J, Maslak V. Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials. in International Journal of Energy Research. 2020;44(2):1294-1302. doi:10.1002/er.4934 .
Jaksić, Jovana, Ostojić, Sanja, Micić, Darko, Vujosević, Zorana Tokic, Milovanović, Jelena, Karkalić, Radovan, O'Connor, Kevin, Kenny, Shane T., Casey, William, Nikodinović-Runić, Jasmina, Maslak, Veselin, "Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials" in International Journal of Energy Research, 44, no. 2 (2020):1294-1302, https://doi.org/10.1002/er.4934 . .