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Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials
dc.creator | Jaksić, Jovana | |
dc.creator | Ostojić, Sanja | |
dc.creator | Micić, Darko | |
dc.creator | Vujosević, Zorana Tokic | |
dc.creator | Milovanović, Jelena | |
dc.creator | Karkalić, Radovan | |
dc.creator | O'Connor, Kevin | |
dc.creator | Kenny, Shane T. | |
dc.creator | Casey, William | |
dc.creator | Nikodinović-Runić, Jasmina | |
dc.creator | Maslak, Veselin | |
dc.date.accessioned | 2022-11-15T15:18:08Z | |
dc.date.available | 2022-11-15T15:18:08Z | |
dc.date.issued | 2020 | |
dc.identifier.issn | 0363-907X | |
dc.identifier.uri | https://imagine.imgge.bg.ac.rs/handle/123456789/1399 | |
dc.description.abstract | In the present work, we describe the chemical synthesis of 3-HFAs as prominent derivatives of fatty acids and assess if they could be applied as phase change materials (PCM). In addition, 3-HFAs were obtained by depolymerization of a bacterial biopolymeric material, polyhydroxyalkanoate. Thermal properties of 3-hydoxyoctanoic, decanoic, and dodecanoic acids are reported for the first time. These materials showed the potential to be applied as PCM in temperature range from 33 degrees C to 66 degrees C. In order to expand the temperature range for application of 3-HFAs as PCM, eutectic mass ratios of three kinds of binary mixtures of 3-HFAs were calculated, and their properties were predicted using the Schroder-van Laar equation. Thermal properties of these mixtures were validated by differential scanning calorimetry (DSC) analysis. These results showed that eutectics considerably expanded the scope of applications of 3-HFAs as PCMs. 3-HFAs originating from biotechnologically obtained polyhydroxyalkanoates also showed potential to be applied in development of PCMs. | en |
dc.publisher | Hoboken : Wiley | |
dc.relation | Bioplastech Industrial Collaboration [BP2017] | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172002/RS// | |
dc.rights | restrictedAccess | |
dc.source | International Journal of Energy Research | |
dc.subject | thermophysical properties | en |
dc.subject | phase change materials | en |
dc.subject | eutectic mixtures | en |
dc.subject | biopolymer | en |
dc.subject | 3-hydroxy fatty acids | en |
dc.title | Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 1302 | |
dc.citation.issue | 2 | |
dc.citation.other | 44(2): 1294-1302 | |
dc.citation.rank | aM21 | |
dc.citation.spage | 1294 | |
dc.citation.volume | 44 | |
dc.identifier.doi | 10.1002/er.4934 | |
dc.identifier.scopus | 2-s2.0-85075197383 | |
dc.identifier.wos | 000495538000001 | |
dc.type.version | publishedVersion |